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Prerequisites: Course Contents Invisible ink .Utilization of coordination chemistry to demonstrate invisible ink in laboratory Color effects due to ligand-exchange in nickel complexesDemonstration of ligand-field strength in the spectrochemical series Color effects in aqueous systems containing divalent 3d metal ionsDemonstration of crystal-field splitting parameters of 3d metal ions Acidic and basic saltsHydrolysis of salts and its consequences Preparation of nitro- and nitrito-pentamminecobalt(III) chlorideLinkage isomers: synthesis and identification using various spectroscopic techniques The preparation of hexamminecobalt(III) chloride and pentammineaquocobalt(III) chlorideSynthesis, isolation and characterization of the complex The preparation of cis-and trans -potassiumdioxalatodiaquochromate(III)Geometrical isomers: synthesis and identification using various spectroscopic techniques Aquation oftrans-dichloro-bis(1,2-diamminoethane)cobalt(III)chlorideInvestigation of acid hydrolysis of the complex The preparation and resolution of tris(ethylenediamine)cobalt(III)ion into its optical antipodesOptical isomers: synthesis, isolation and characterization Preparation of hexamminenickel(II) chloride: estimation of ammonia and nickel by titrimetric and gravimetric methodsDetermination of complex composition using simple techniques Synthesis and reactions of organo cobaloximesSynthesis of an air-sensitive organometallic complex at low temperature under inert atmosphere Synthesis and characterization of ferrocene and acetylferroceneSynthesis, purification using chromatography and characterization
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